Cobalt-based Alloy 20
I. Standards and brand system
1. Implementing standards
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International norms:
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Aviation/military industry: AMS 5898 (aviation material specification, defining chemical/mechanical properties of forgings and bars), SAE J467 (automotive engineering standard, specifying technical requirements for wear-resistant parts);
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General Reference: ASTM B438 (General Specification for Cobalt-based Alloy Bars, Auxiliary Test for Composition and Properties).
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Domestic adaptation: there is no completely equivalent brand, and the composition of similar cobalt-based wear-resistant alloys (such as Co-based Cr30W5) is different, so it is necessary to refer to the international standard design.
II. Chemical composition (mass fraction%, typical range)
| element | Content range | Core role |
|---|---|---|
| C | 0.7~3.0 | Forming hard phases of Cr₇C₃ and WC with Cr/W to improve wear resistance (carbon content =→ hardness =, plasticity ↓). |
| Co | 30~70 | Stabilize the matrix at high temperature to provide toughness and corrosion resistance. |
| Cr | 25~33 | Cr₂O₃ oxide film is formed, which is resistant to high temperature oxidation and acid/alkali/seawater corrosion; Cr₇C₃ carbide is also generated. |
| W | 3~25 | WC/WC hard phase (hardness HV1500+) is precipitated, which significantly improves the wear resistance. |
| Fe/Ni | ≤3.0 | Impurity elements, exceeding the limit to reduce corrosion resistance (strict control) |
III. Mechanical properties (typical value, as-cast/annealed)
| Performance index | typical value | Contrast 316L stainless steel. |
|---|---|---|
| tensile strength | 700~1000 MPa | 17% higher (316l ≈ 600mpa) |
| yield strength | 300~600 MPa | 100% higher (316L≈310 MPa) |
| extensibility(δ₅) | 3~10% | 75% lower(316L≈40%) |
| hardness | 55~60 HRC | 175% higher (316L≈20 HRC) |
| heat resistance | Long term tolerance 1000℃ | 150% higher (316L 长期≤400℃) |
IV. Requirements for Heat Treatment and Processing
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Heat treatment (optimizing structure and releasing property):
- Stress relieving after casting: heat preservation at 800~900℃ for 2~4 hours, air cooling (stabilizing carbide distribution, eliminating casting stress and preventing cracking);
- Repair after welding: preheat 300~400℃ before welding (cobalt-based alloy has poor thermal conductivity to prevent hot cracking), adopt TIG/MIG welding (ERCoCr welding wire), and anneal at 750~850℃ after welding (repair heat affected zone and restore corrosion resistance).
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Machining characteristics (high hardness challenge):
- Casting: lost wax casting is preferred (precision molding of valve seats, nozzles and other complex parts);
- Machining: cubic boron nitride (CBN)/ diamond tool, low speed+high pressure cooling (to avoid tool wear, the surface roughness should be Ra ≤ 1.6μ m);
- Surfacing: it is often used for surface strengthening (such as valve sealing surface, which can improve the wear life by 5 times).
V. Main application fields (“ultimate solution” for extreme working conditions)
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Energy and chemical industry:
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Valves/seals: valve seat of blowout preventer for oil drilling, plunger of chemical pump (resistant to high-pressure mud+acid and alkali corrosion, with life exceeding 3 times that of tungsten carbide);
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High-temperature components: geothermal well pipes, gas turbine combustion chamber liners (resistant to 1000℃ high temperature+corrosion, replacing nickel-based alloy to reduce cost by 40%).
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Aerospace:
- Engine: turbine blade edge (anti-800℃ gas erosion, wear life is twice that of titanium alloy), landing gear hinge bushing (high impact+wear resistance);
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Machinery and tools:
- Wear-resistant parts: hammer head of mine crusher, bushing of mill housing (wear-resistant, life is 5 times of ultra-high manganese steel);
- Cutting tools: tool tips made of hard-to-machine materials (dry cutting and wear resistance, life is 3 times longer than that of cemented carbide);
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Medical field:
- Implants: artificial joint ball head (wear-resistant+biocompatible, life is over 20 years, replacing ceramics to reduce cost by 50%), dental implant (body fluid corrosion resistance).
Key summary
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Core advantages:
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Wear-resistant ceiling: the proportion of carbide is over 30%, the hardness is ≥55 HRC, and the abrasive/adhesive wear resistance is 10 times higher than that of stainless steel;
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All-environment corrosion resistance: the corrosion rate in acid and alkali, seawater and high-temperature gas is less than 0.01 mm/year;
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No softening at high temperature: the strength is still maintained at 1000℃, which is far better than that of conventional alloys.
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Limited challenges:
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Cost-sensitive (cobalt price accounts for 70%, and the price fluctuates greatly);
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Complex processing (high hardness requires special technology, and the manufacturing cost increases by 50%).
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