F310


F310 is a high chromium-nickel austenitic heat-resistant stainless steel, and its core advantages are high temperature oxidation resistance (long-term stability at 1100℃) and high temperature strength. The following are analyzed from standards, codes, compositions, properties, heat treatment and application systems:

I. Standards and brand system

1. Core standards

F310 mainly follows ASTM standards and covers multi – form products:
  • Forgings: ASTM A182 (defines “F310”, used for high – temperature flanges and pipes);
  • Plates/strips: ASTM A240 (for pressure vessels, furnace linings, etc.);
  • Tubes: ASTM A312 (for seamless/welded high – temperature pipelines);

    It is also compatible with international standards such as ASME (e.g., SB446 tubes), ISO (e.g., 9723 bars), and EN 10095 (profiles).

2. International brand correspondence

System/Region Grade Description
US UNS UNS S31000 Basic type F310
European EN 1.4821 Equivalent to F310
Japanese JIS SUH310 Heat – resistant optimized type (focus on high temperature)
Chinese GB 20Cr25Ni20 Old grade, austenitic heat – resistant steel

II. Chemical composition (ASTM standard, mass fraction%)

F310 achieves high – temperature oxidation resistance through “high Cr – Ni synergy”:


Element Content Range Function Analysis
C ≤0.25 A small amount of carbon increases high – temperature strength (needs to be controlled to prevent intergranular corrosion)
Si ≤1.00 Deoxidizes and assists in oxidation resistance
Mn ≤2.00 Stabilizes austenite and improves workability
P ≤0.045 Impurity, strictly controlled to reduce embrittlement risk
S ≤0.030 Impurity, low sulfur ensures corrosion resistance
Cr 24.0 – 26.0 Forms a dense Cr₂O₃ film, resisting oxidation at 1100°C (core!)
Ni 19.0 – 22.0 Stabilizes austenite and improves high – temperature toughness

III. Mechanical properties (room temperature after solution treatment)

F310 has both high – temperature strength and room – temperature plasticity:


Performance Indicator Typical Value (ASTM Requirement) Remarks
Tensile Strength ≥515 MPa Still ≥200 MPa at 800°C, excellent creep resistance
Yield Strength (σ₀.₂) ≥205 MPa Austenitic alloy has low yield strength and can be strengthened by cold working
Elongation (δ₅) ≥30% Gauge length 50mm, meets forming requirements (pipe bending, forging)
Hardness ≤223 HB (or ≤95 HRB) Hardness increases significantly after cold working (e.g., cold – rolled plate can reach 250 HB)

IV. Heat Treatment Requirements

The core is “solution annealing” to dissolve carbides and restore performance:
  1. Solution Treatment:
  • Temperature: 1030 – 1180°C (1050 – 1150°C is recommended to ensure complete dissolution of carbides);
  • Cooling: Rapid water cooling (quenching) to obtain a single austenitic structure;
  • Application: Mandatory before delivery; re – solution treatment is required after welding (to prevent sensitization of thick – walled parts).

V. Main application fields (high temperature oxidation scene)

Relying on the core advantage of “long – term oxidation resistance at 1100°C”, it focuses on:
  1. High – temperature Industrial Furnaces:
  • Furnace bottom plates, furnace rolls, radiant tubes (resistant to oxidation in furnaces at 1000 – 1100°C, such as heat treatment furnaces and roasting furnaces).
  1. Energy and Environmental Protection:
  • Heat – affected surfaces of waste incinerators (resistant to HCl, dust + high – temperature corrosion);
  • Boiler superheater tubes (resistant to high – temperature steam oxidation, replacing some nickel – based alloys).
  1. Chemical Industry and Metallurgy:
  • High – temperature reaction kettles (such as parts of 磷酸铁锂 roasting furnaces, resistant to high temperatures above 800°C);
  • Metallurgical continuous casting rolls (resistant to molten steel splashing + high – temperature wear).
  1. Special Fields:
  • Glass melting furnace parts (resistant to glass liquid erosion + high – temperature oxidation);
  • Aviation engine test pieces (to verify high – temperature performance).

VI. Key Contrast and Precautions

  1. vs 310S (UNS S31008, low – carbon version):
  • F310 (C ≤ 0.25%) has slightly higher high – temperature strength, while 310S (C ≤ 0.08%) has better resistance to intergranular corrosion (suitable for welding scenarios).
  1. Corrosion limitations:
  • Prone to pitting in wet environments containing chloride ions (replace with 316L/duplex steel);
  • Avoid the 450 – 850°C sensitization range (carbide precipitation reduces corrosion resistance).
  1. Processing tips:
  • Can be strengthened by cold working, but softens easily at high temperatures;
  • Use ER310 welding wire for welding, and solution treatment is recommended after welding thick plates.


F310 is a “benchmark austenitic steel for high – temperature oxidation resistance”. It breaks through the temperature upper limit of conventional stainless steel through high Cr – Ni and is irreplaceable in high – temperature fields such as industrial furnaces and energy. The division of labor with 310S is clear: F310 focuses on high – temperature strength, while 310S focuses on corrosion resistance, and selection should be made as needed.
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